SubstancesRestricted substance

Polybrominated Diphenyl Ethers (PBDE)

A family of brominated flame retardants restricted under RoHS at 0.1 percent, with DecaBDE additionally controlled under the POP Regulation and REACH Annex XVII.

Updated
2026-06-12

Overview

Polybrominated diphenyl ethers are a family of brominated flame retardants. They are persistent and build up in living organisms, which is why they face restrictions beyond electronics. DecaBDE is the best-known member.

CAS
Varies by congener (DecaBDE is 1163-19-5)
Limit
0.1 percent per homogeneous material (RoHS)
Why restricted
Persistent, bioaccumulative brominated flame retardants
Typical use
Flame retardants in plastics and textiles

Where it's restricted

Under RoHS PBDEs are capped at 0.1 percent by weight per homogeneous material. DecaBDE, a common member of the family, also falls under the POP Regulation and is restricted by REACH Annex XVII.

The closely related biphenyls are covered separately in PBB.

Typical uses

PBDEs were added as flame retardants to plastics and textiles. Several members have been phased out, and DecaBDE now sits under multiple overlapping controls.

Key point

DecaBDE shows how one substance can be hit by several regimes at once. RoHS, POP and REACH all apply, and the strictest rule governs.

Note: this is general educational information and not legal advice. Always check the official source before relying on it.

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Related entries

RoHSflame retardantbrominatedPOP