SubstancesClass of concern

Brominated Flame Retardants (BFR)

A class of bromine-based flame retardants added to plastics and electronics, including PBB, PBDE, HBCDD and TBBPA, whose persistence and dioxin risk drive the move to halogen-free.

Updated
2026-06-12

Overview

Brominated flame retardants are a class of bromine-based chemicals added to plastics, electronics and textiles to slow ignition. They work well and are cheap, which is why they spread through circuit boards, housings, cables and upholstery. The family includes PBB, PBDE, HBCDD and TBBPA. Each carries its own regulatory history, but they share the same broad concerns.

What
Bromine-based flame retardants
Members
PBB, PBDE, HBCDD, TBBPA
Concern
Persistence, bioaccumulation, brominated dioxins on burning
Typical use
Plastics, electronics, textiles

Why they are a concern

Three problems recur across the family. They are persistent, so they linger in the environment. They are bioaccumulative, so they build up in living organisms. And when products containing them are burned, they can form brominated dioxins, which are highly toxic. These traits are what pushed regulators to act.

How they are regulated

The controls are spread across several rules. RoHS restricts PBB and PBDE in electrical and electronic equipment. HBCDD is controlled as a persistent organic pollutant, and TBBPA sits on the REACH Candidate List. So a single flame-retardant additive may fall under different regimes depending on which member it is.

Key point

These concerns drive the move to halogen-free electronics, where bromine and chlorine are kept below set thresholds rather than relying on brominated additives.

Note: general educational information, not legal advice. Check the official source before relying on it.

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Related entries

RoHSREACHPOPflame retardantbrominated